Bismuth Nitrate Extra Pure

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Bismuth Nitrate Extra Pure is a high-purity inorganic compound composed of bismuth and nitrate ions, typically supplied as a crystalline solid or powder. It is widely used as a precursor in chemical synthesis, pharmaceuticals, cosmetics, and industrial applications. Known for its excellent solubility in nitric acid and water, this compound serves as a source of bismuth ions in various chemical reactions and formulations. Its high purity ensures minimal impurities, making it suitable for sensitive applications requiring consistent quality and performance.

Description

 

  • USES

Primary Uses

  1. Reagent in Qualitative Inorganic Analysis

    • Used for detecting sulfide ions by forming a black bismuth sulfide (Biâ‚‚S₃) precipitate — a classical spot test in qualitative analysis.

  2. Precursor for Bismuth-Based Compounds

    • Serves as a starting material in the synthesis of bismuth oxide, bismuth subnitrate, or bismuth-containing catalysts in research labs.

  3. Oxidizing Agent in Organic Synthesis

    • Occasionally employed in lab-scale oxidative transformations, such as alcohol oxidation or cleavage of C–C bonds.

  4. Component in Catalysis Studies

    • Investigated in heterogeneous catalysis, particularly in the formation of nano-bismuth oxide materials for photocatalytic or environmental applications.

Secondary Uses

  1. Pigment Chemistry Research

    • Used in experiments replicating historic pigment production (e.g., bismuth white) for art conservation or chemical heritage studies.

  2. Educational Demonstrations

    • Demonstrates nitrate decomposition (releasing NOx gases) or precipitation reactions with various anions in advanced chemistry classes.

  3. Glass & Ceramic Lab Experiments

    • Occasionally used in the formulation of specialty glass or ceramic glazes containing bismuth, often at research or prototyping scale.

  4. Coordination Chemistry Studies

    • Forms bismuth-ligand complexes studied in metal-ligand interaction research or crystallography.
Product Key Features

KEY ATTRIBUTES

1. Basic Identification Attributes

  • Chemical Name: Bismuth(III) nitrate pentahydrate

  • CAS Number: 10035-06-0

  • HS Code: 2834.29.90 (Other nitrates, Bismuth compound)

  • Molecular Formula: Bi(NO₃)₃·5Hâ‚‚O

  • Synonyms:

    • Bismuth trinitrate

    • Bismuth nitrate pentahydrate

    • Nitric acid, bismuth(3+) salt, pentahydrate

2. Physical & Chemical Properties

  • Physical State: Solid (crystalline powder)

  • Color & Odor: White to pale yellow; faint nitric acid odor

  • Boiling Point: Decomposes before boiling

  • Melting Point: ~30 °C (softens/decomposes)

  • Density: ~2.83 g/cm³ (solid)

  • Solubility:

    • Water: Soluble (forms acidic solution)

    • Alcohol: Slightly soluble

  • pH Level: ~1–2 (1% aqueous solution, acidic)

  • Vapor Pressure: Negligible at room temperature

  • Flash Point: Not flammable

  • Autoignition Temperature: Not applicable

  • Viscosity: Not applicable (solid)

3. Safety & Hazard Attributes

  • Hazard Class (GHS):

    • Oxidizing Solid (Category 3)

    • Acute Toxicity – Oral (Category 4)

    • Skin Irritation (Category 2)

    • Eye Irritation (Category 2A)

    • Hazardous to Aquatic Environment (Chronic – Category 3)

  • GHS Pictograms:


  • NFPA Ratings:

    • Health: 2

    • Flammability: 0

    • Reactivity: 1

  • Exposure Limits:

    • No specific OSHA PEL or ACGIH TLV for bismuth nitrate; avoid prolonged exposure

  • Reactivity:

    • Reacts with organic materials, reducing agents

    • Decomposes when heated, releasing toxic NOâ‚“ gases

4. Storage & Handling Attributes

  • Storage Conditions:

    • Store in a cool, dry, well-ventilated area

    • Keep container tightly sealed and away from heat and light

  • Incompatible Materials:

    • Organic substances

    • Reducing agents

    • Combustible materials

  • Container Type:

    • Use chemical-resistant glass or plastic containers

  • Shelf Life:

    • Stable for at least 2 years if properly stored

  • Special Handling Requirements:

    • Use gloves and eye protection

    • Handle in fume hood to avoid inhalation of acid vapors or NOâ‚“

5. Regulatory & Compliance Attributes

  • Regulatory Status:

    • Listed under REACH and TSCA (U.S.)

    • Not listed as a controlled substance

  • Transportation Restrictions:

    • UN Number: UN 1477 (Nitrates, inorganic, n.o.s.)

    • Hazard Class: 5.1 (Oxidizer)

    • Packing Group: III

  • Waste Disposal Method:

    • Dispose in accordance with local environmental regulations

    • Considered hazardous waste (U.S. EPA)

    • Avoid release to water systems

6. Environmental & Health Impact

  • Ecotoxicity:

    • Harmful to aquatic organisms; avoid environmental release

  • Persistence in Environment:

    • Bismuth is not highly mobile but accumulates in sediments

  • Carcinogenicity/Mutagenicity:

    • Not classified as carcinogenic by IARC, ACGIH, or NTP

  • Biodegradability:

    • Inorganic compound – not biodegradable
Safety Handling Precautions

SAFETY PRECAUTIONS

  1. Personal Protective Equipment (PPE):

    • Wear lab coat, chemical-resistant gloves, and safety goggles.

    • Use in a well-ventilated area or under a fume hood to avoid inhalation.

  2. Handling:

    • Handle with care to avoid dust formation and inhalation.

    • Avoid contact with skin, eyes, and clothing.

    • Do not ingest or inhale.

  3. Storage:

    • Store in a tightly sealed container.

    • Keep in a cool, dry, well-ventilated area.

    • Protect from light, moisture, and incompatible substances (e.g., strong reducing agents or organics).

  4. Hygiene Measures:

    • Wash hands thoroughly after use.

    • Do not eat or drink in chemical handling areas.

FIRST AID MEASURES

  1. Inhalation:

    • Move the person to fresh air immediately.

    • If breathing is difficult, provide oxygen.

    • Seek medical attention if symptoms develop.

  2. Skin Contact:

    • Rinse thoroughly with soap and water.

    • Remove contaminated clothing and seek medical help if irritation develops.

  3. Eye Contact:

    • Rinse cautiously with plenty of water for 15 minutes.

    • Seek medical attention if irritation or pain persists.

  4. Ingestion:

    • Rinse mouth thoroughly with water.

    • Do not induce vomiting.

    • Get immediate medical help.

FIRE FIGHTING MEASURES

  1. Extinguishing Media:

    • Use dry chemical, COâ‚‚, or alcohol-resistant foam.

    • Water spray may be used to cool containers, but avoid direct contact with water if the substance is reacting.

  2. Fire Hazards:

    • Oxidizing agents – may enhance combustion of other materials.

    • Decomposes at high temperatures producing toxic gases (e.g., nitrogen oxides, bismuth oxides).

  3. Protective Equipment:

    • Wear self-contained breathing apparatus (SCBA) and full firefighting protective gear.