SPECIALTY AND FINE CHEMICALS

BORIC ACID: THE MULTIFUNCTIONAL MINERAL ACID WITH SURPRISING APPLICATIONS

Boric acid (H₃BO₃) is a weak, naturally occurring acid that serves as an unsung hero across industries. From antiseptics to nuclear reactors, this white crystalline powder demonstrates remarkable versatility. Unlike strong acids, boric acid is mild yet effective, making it ideal for sensitive applications in medicine, agriculture, and manufacturing.

Key Properties & Production

Physical & Chemical Characteristics

  • Appearance: White, odorless powder or crystals
  • Solubility:
    • 4.7 g/100 mL (cold water)
    • 27.5 g/100 mL (boiling water)
  • pH: ~5.1 (weakly acidic)
  • Melting Point: 170°C (decomposes to boron trioxide)

Production Methods

  1. From Borax (Most Common)
    • Reacting borax (Naâ‚‚Bâ‚„O₇) with a mineral acid (e.g., HCl or Hâ‚‚SOâ‚„)
    • Reaction: Naâ‚‚Bâ‚„O₇ + 2HCl + 5Hâ‚‚O → 4H₃BO₃ + 2NaCl
  2. From Colemanite (Calcium borate mineral)
  3. Byproduct Recovery (From boron-rich geothermal waters)

Major Applications

1. Pest Control & Antiseptics

  • Insecticide: Kills roaches, ants, and termites by disrupting metabolism
  • Antifungal: Treats yeast infections (e.g., vaginal suppositories)
  • Eye Wash: 2.5% solution for mild eye irritation

2. Industrial & Manufacturing

  • Flame Retardant: Used in cellulose insulation and textiles
  • Glass & Ceramics:
    • Strengthens Pyrex® glass
    • Improves glaze adhesion in ceramics
  • Nuclear Power: Neutron absorber in reactor control rods

3. Agriculture & Wood Preservation

  • Micronutrient Fertilizer: Corrects boron deficiency in crops
  • Wood Protection: Prevents fungal decay in timber

4. Personal Care & Cosmetics

  • Preservative: Extends shelf life of lotions and creams
  • Acne Treatment: Mild antibacterial properties

5. Metalworking & Welding

  • Flux Agent: Removes oxides during soldering and welding

Safety & Environmental Impact

✅ Low Acute Toxicity (Less corrosive than strong acids)
âš  Chronic Exposure Risks:

  • Hormonal disruption at high doses
  • Kidney damage with prolonged ingestion
    âš  Environmental Concerns:
  • Toxic to aquatic life at high concentrations
  • Banned in EU cosmetics (except for preserved products)

Market Trends & Future Outlook

  • Global Demand: 1.8 million tons/year (growing at 4.1% CAGR)
  • Key Drivers:
    • Expanding nuclear energy sector
    • Rising need for eco-friendly flame retardants
  • Innovations:
    • Nano-boric acid for enhanced lubrication
    • Bio-based production from plant extracts

Conclusion

Boric acid bridges ancient remedies and cutting-edge technology, proving that simple chemistry can solve complex problems. As industries prioritize mild yet effective solutions, this mineral acid’s role will continue expanding—from protecting homes to powering reactors.