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Aqeous Ammonia Solution Extra Pure

Original price was: $ 30.00.Current price is: $ 29.45.

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Aqeous Ammonia Solution Extra Pure is a high-purity, clear, colorless liquid consisting of ammonia gas dissolved in water, emitting a strong, characteristic odor. It is widely used in laboratory chemistry as a weak base and complexing agent in acid-base titrations, buffer preparation, and qualitative inorganic analysis, particularly for detecting metal ions through complex formation. It also plays a role in pH adjustment, sample preparation, and synthesis of ammonium compounds. The extra pure grade ensures low levels of impurities, making it ideal for sensitive analytical procedures and high-precision research. Due to its volatility and corrosive nature, it should be handled in well-ventilated areas and stored in tightly sealed, chemical-resistant containers away from heat and direct sunlight.

Description

Aqeous Ammonia Solution Extra Pure

Primary Uses

  1. Alkaline Reagent and pH Adjuster
    • Commonly used to raise pH in titrations, buffer preparation, and general aqueous reactions.
  2. Complexing Agent in Inorganic Analysis
    • Forms ammonia complexes with metal ions (e.g., Cu²⁺, Ag⁺, Ni²⁺), aiding in qualitative analysis and separation of cations.
  3. Precipitant in Group III and IV Inorganic Qualitative Analysis
    • Used to precipitate metal hydroxides such as Fe(OH)₃, Al(OH)₃, Zn(OH)₂ under controlled pH.
  4. Neutralizing Agent in Acid–Base Titrations
    • A weak base used in titrations and buffer studies, especially for demonstrating weak base–strong acid behavior.
  5. Preparation of Ammonium Salts and Lab Reagents
    • Reacts with acids or acidic oxides to form ammonium salts (e.g., NH₄Cl, NH₄NO₃) for synthesis or calibration.

Secondary Uses

  1. Cleaning Agent for Glassware and Electrodes
    • Removes organic residues or metal deposits from lab equipment, especially when combined with peroxide or acids (used with caution).
  2. Reagent in Nessler’s Test for Ammonia Detection
    • Forms colored complex with Nessler’s reagent — useful in trace ammonia or nitrogen analysis.
  3. Reducing Agent in Redox Systems (Mild Conditions)
    • In select systems, can act as a reducing agent or participate in redox equilibria (e.g., silver oxide reduction).
  4. Ligand in Coordination Complex Synthesis
    • Introduces labile NH₃ ligands into metal centers in coordination and transition metal chemistry studies.
  5. Demonstration of Gas Solubility and Equilibrium
    • Used to show Henry’s Law, dynamic equilibria, and acid–base gas absorption phenomena.

 

Additional information
PACK SIZE

2.5 Litres Glass bottle

KEY PRODUCT FEATURES

1. Basic Identification Attributes

  • Chemical Name: Ammonia Solution (Aqueous Ammonia)
  • CAS Number: 1336-21-6
  • HS Code: 28142000 (Ammonia in aqueous solution)
  • Molecular Formula: NH₄OH (often written, though it exists in equilibrium as NH₃ + H₂O)
  • Synonyms:
    • Aqueous ammonia
    • Ammonium hydroxide
    • Aqua ammonia
    • Ammonia water

2. Physical & Chemical Properties

  • Physical State: Liquid
  • Color & Odor: Colorless liquid with a strong pungent, ammonia-like odor
  • Boiling Point: ~27–33 °C (for concentrated solutions)
  • Melting Point: ~−57.5 °C
  • Density/Specific Gravity: ~0.91 g/cm³ (for ~25–30% NH₃ solution)
  • Solubility:
    • Water: Completely miscible
    • Ethanol: Soluble
  • pH Level: ~11.6–12.5 (depending on concentration)
  • Vapor Pressure: High – releases ammonia gas readily
  • Flash Point: Not flammable, but ammonia vapors are flammable in air (~651 °C autoignition)
  • Autoignition Temperature: ~651 °C
  • Viscosity: ~0.88 mPa·s

3. Safety & Hazard Attributes 

  • Hazard Class (GHS):
    • Skin Corrosion/Irritation (Category 2)
    • Serious Eye Damage (Category 1)
    • Aquatic Toxicity – Acute & Chronic (Category 2)
  • NFPA Ratings:
    • Health: 3
    • Flammability: 1
    • Reactivity: 0
  • Exposure Limits:
    • OSHA PEL: 50 ppm (35 mg/m³)
    • ACGIH TLV: 25 ppm TWA, 35 ppm STEL
  • Reactivity:
    • Reacts with acids, oxidizers, and halogens
    • Can form explosive mixtures with air at high concentrations

4. Storage & Handling Attributes

  • Storage Conditions:
    • Store in a cool, well-ventilated area away from heat and acids
    • Keep containers tightly sealed to prevent gas escape
  • Incompatible Materials:
    • Acids, halogens (e.g., chlorine), hypochlorites, strong oxidizers, metals like copper and zinc
  • Container Type:
    • Vented HDPE plastic or glass bottles
  • Shelf Life & Expiration Date:
    • ~1 year (ammonia concentration decreases over time)
  • Special Handling Requirements:
    • Use chemical-resistant gloves, goggles, and lab coat
    • Work under fume hood due to strong vapors

5. Regulatory & Compliance Attributes 

  • Regulatory Status:
    • Listed in TSCA, REACH, and regulated under OSHA, DOT
  • Transportation Restrictions:
    • UN Number: UN 2672
    • Hazard Class: 8 (Corrosive), Packing Group III
  • Waste Disposal Method:
    • Neutralize with dilute acid under controlled conditions
    • Dispose through certified hazardous waste handler

6. Environmental & Health Impact

  • Ecotoxicity:
    • Very toxic to aquatic life due to pH elevation and ammonia toxicity
  • Persistence in Environment:
    • Volatile, but ammonia can accumulate in enclosed systems
  • Carcinogenicity/Mutagenicity:
    • Not classified as carcinogenic
  • Biodegradability:
    • Inorganic; ammonia is naturally assimilated by soil and plants but in excess is harmful
SAFETY HANDLING PRECAUTIONS

SAFETY PRECAUTIONS 

  1. Personal Protective Equipment (PPE):
    • Wear:
      • Lab coat
      • Chemical splash goggles
      • Nitrile or neoprene gloves
      • Face shield (for large volumes or risk of splashing)
    • Use only in a fume hood—vapors are sharp and irritating.
  2. Handling:
    • Avoid inhalation of vapors.
    • Prevent contact with skin, eyes, or clothing.
    • Open containers carefully—ammonia fumes are volatile and corrosive.
    • Never mix with acids—can cause violent reactions and release large amounts of ammonia gas.
  3. Storage:
    • Keep in a tightly sealed container in a cool, well-ventilated place.
    • Store away from:
      • Acids
      • Oxidizing agents
      • Heat and direct sunlight
    • Use corrosion-resistant storage containers (e.g., HDPE).
  4. Hygiene Measures:
    • Wash hands after handling.
    • Avoid touching your face or eyes while working with the solution.
    • Clean surfaces thoroughly after spills or use.

FIRST AID MEASURES

  1. Inhalation:
    • Move the person to fresh air immediately.
    • Loosen tight clothing and ensure open airways.
    • Provide oxygen if breathing is labored.
    • Seek urgent medical attention—vapors may cause respiratory irritation or lung damage.
  2. Skin Contact:
    • Remove contaminated clothing.
    • Rinse skin with plenty of water for at least 15 minutes.
    • Seek medical attention if irritation or burns develop.
  3. Eye Contact:
    • Rinse cautiously with water for at least 15 minutes, holding eyelids apart.
    • Remove contact lenses if present and easy to do.
    • Seek immediate medical attention—can cause severe eye burns and permanent damage.
  4. Ingestion:
    • Rinse mouth thoroughly with water.
    • Do not induce vomiting.
    • Give water or milk if the person is fully conscious.
    • Seek emergency medical care—ingestion can result in burns to the mouth, throat, and stomach.

FIRE FIGHTING MEASURES

  1. Extinguishing Media:
    • Use dry chemicals, CO₂, alcohol-resistant foam, or water spray.
    • Do not use water jets directly on ammonia tanks.
  2. Fire Hazards:
    • Not flammable, but heating can release flammable ammonia gas.
    • Containers may rupture under heat due to vapor pressure.
    • Thermal decomposition can release:
      • Ammonia (NH₃)
      • Nitrogen oxides (NOₓ)
  3. Protective Equipment:
    • Firefighters must wear self-contained breathing apparatus (SCBA) and full protective clothing.
  4. Firefighting Instructions:
    • Cool fire-exposed containers with water spray.
    • Approach from upwind to avoid vapors.
    • Prevent runoff from entering drains—toxic to aquatic life.