Bismuth Nitrate Extra Pure
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Bismuth Nitrate Extra Pure is a high-purity inorganic compound composed of bismuth and nitrate ions, typically supplied as a crystalline solid or powder. It is widely used as a precursor in chemical synthesis, pharmaceuticals, cosmetics, and industrial applications. Known for its excellent solubility in nitric acid and water, this compound serves as a source of bismuth ions in various chemical reactions and formulations. Its high purity ensures minimal impurities, making it suitable for sensitive applications requiring consistent quality and performance.
Description
- USES
Table of Contents
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Primary Uses
- Reagent in Qualitative Inorganic Analysis
- Used for detecting sulfide ions by forming a black bismuth sulfide (Bi₂S₃) precipitate — a classical spot test in qualitative analysis.
- Precursor for Bismuth-Based Compounds
- Serves as a starting material in the synthesis of bismuth oxide, bismuth subnitrate, or bismuth-containing catalysts in research labs.
- Oxidizing Agent in Organic Synthesis
- Occasionally employed in lab-scale oxidative transformations, such as alcohol oxidation or cleavage of C–C bonds.
- Component in Catalysis Studies
- Investigated in heterogeneous catalysis, particularly in the formation of nano-bismuth oxide materials for photocatalytic or environmental applications.
Secondary Uses
- Pigment Chemistry Research
- Used in experiments replicating historic pigment production (e.g., bismuth white) for art conservation or chemical heritage studies.
- Educational Demonstrations
- Demonstrates nitrate decomposition (releasing NOx gases) or precipitation reactions with various anions in advanced chemistry classes.
- Glass & Ceramic Lab Experiments
- Occasionally used in the formulation of specialty glass or ceramic glazes containing bismuth, often at research or prototyping scale.
- Coordination Chemistry Studies
- Forms bismuth-ligand complexes studied in metal-ligand interaction research or crystallography.
Product Key Features
KEY ATTRIBUTES
1. Basic Identification Attributes
- Chemical Name: Bismuth(III) nitrate pentahydrate
- CAS Number: 10035-06-0
- HS Code: 2834.29.90 (Other nitrates, Bismuth compound)
- Molecular Formula: Bi(NO₃)₃·5H₂O
- Synonyms:
- Bismuth trinitrate
- Bismuth nitrate pentahydrate
- Nitric acid, bismuth(3+) salt, pentahydrate
2. Physical & Chemical Properties
- Physical State: Solid (crystalline powder)
- Color & Odor: White to pale yellow; faint nitric acid odor
- Boiling Point: Decomposes before boiling
- Melting Point: ~30 °C (softens/decomposes)
- Density: ~2.83 g/cm³ (solid)
- Solubility:
- Water: Soluble (forms acidic solution)
- Alcohol: Slightly soluble
- pH Level: ~1–2 (1% aqueous solution, acidic)
- Vapor Pressure: Negligible at room temperature
- Flash Point: Not flammable
- Autoignition Temperature: Not applicable
- Viscosity: Not applicable (solid)
3. Safety & Hazard Attributes
- Hazard Class (GHS):
- Oxidizing Solid (Category 3)
- Acute Toxicity – Oral (Category 4)
- Skin Irritation (Category 2)
- Eye Irritation (Category 2A)
- Hazardous to Aquatic Environment (Chronic – Category 3)
- GHS Pictograms:
- NFPA Ratings:
- Health: 2
- Flammability: 0
- Reactivity: 1
- Exposure Limits:
- No specific OSHA PEL or ACGIH TLV for bismuth nitrate; avoid prolonged exposure
- Reactivity:
- Reacts with organic materials, reducing agents
- Decomposes when heated, releasing toxic NOâ‚“ gases
4. Storage & Handling Attributes
- Storage Conditions:
- Store in a cool, dry, well-ventilated area
- Keep container tightly sealed and away from heat and light
- Incompatible Materials:
- Organic substances
- Reducing agents
- Combustible materials
- Container Type:
- Use chemical-resistant glass or plastic containers
- Shelf Life:
- Stable for at least 2 years if properly stored
- Special Handling Requirements:
- Use gloves and eye protection
- Handle in fume hood to avoid inhalation of acid vapors or NOâ‚“
5. Regulatory & Compliance Attributes
- Regulatory Status:
- Listed under REACH and TSCA (U.S.)
- Not listed as a controlled substance
- Transportation Restrictions:
- UN Number: UN 1477 (Nitrates, inorganic, n.o.s.)
- Hazard Class: 5.1 (Oxidizer)
- Packing Group: III
- Waste Disposal Method:
- Dispose in accordance with local environmental regulations
- Considered hazardous waste (U.S. EPA)
- Avoid release to water systems
6. Environmental & Health Impact
- Ecotoxicity:
- Harmful to aquatic organisms; avoid environmental release
- Persistence in Environment:
- Bismuth is not highly mobile but accumulates in sediments
- Carcinogenicity/Mutagenicity:
- Not classified as carcinogenic by IARC, ACGIH, or NTP
- Biodegradability:
- Inorganic compound – not biodegradable
Safety Handling Precautions
SAFETY PRECAUTIONS
- Personal Protective Equipment (PPE):
- Wear lab coat, chemical-resistant gloves, and safety goggles.
- Use in a well-ventilated area or under a fume hood to avoid inhalation.
- Handling:
- Handle with care to avoid dust formation and inhalation.
- Avoid contact with skin, eyes, and clothing.
- Do not ingest or inhale.
- Storage:
- Store in a tightly sealed container.
- Keep in a cool, dry, well-ventilated area.
- Protect from light, moisture, and incompatible substances (e.g., strong reducing agents or organics).
- Hygiene Measures:
- Wash hands thoroughly after use.
- Do not eat or drink in chemical handling areas.
FIRST AID MEASURES
- Inhalation:
- Move the person to fresh air immediately.
- If breathing is difficult, provide oxygen.
- Seek medical attention if symptoms develop.
- Skin Contact:
- Rinse thoroughly with soap and water.
- Remove contaminated clothing and seek medical help if irritation develops.
- Eye Contact:
- Rinse cautiously with plenty of water for 15 minutes.
- Seek medical attention if irritation or pain persists.
- Ingestion:
- Rinse mouth thoroughly with water.
- Do not induce vomiting.
- Get immediate medical help.
FIRE FIGHTING MEASURES
- Extinguishing Media:
- Use dry chemical, COâ‚‚, or alcohol-resistant foam.
- Water spray may be used to cool containers, but avoid direct contact with water if the substance is reacting.
- Fire Hazards:
- Oxidizing agents – may enhance combustion of other materials.
- Decomposes at high temperatures producing toxic gases (e.g., nitrogen oxides, bismuth oxides).
- Protective Equipment:
- Wear self-contained breathing apparatus (SCBA) and full firefighting protective gear.
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