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Calcium Saccharin
Calcium Saccharin is the calcium salt form of saccharin, a synthetic sweetener. It appears as a white to off-white crystalline powder with a sweet taste that is several hundred times sweeter than sucrose (table sugar). Calcium Saccharin is water-soluble and widely used as a non-nutritive sweetener in food and beverage products, pharmaceuticals, and oral care formulations. Due to its stability under heat and acidic conditions, it is ideal for baked goods and beverages. It serves as a sugar substitute for diabetic and calorie-restricted diets and is often used in combination with other sweeteners to improve taste profiles.
Calcium Saccharin
Primary Uses
- Food Industry
- Used as a high-intensity, calorie-free sweetener in soft drinks, candies, baked goods, and other processed foods.
- Serves as a sugar substitute for diabetic-friendly and low-calorie foods.
- Enhances sweetness without contributing to tooth decay or calories.
- Pharmaceuticals
- Incorporated as a sweetening agent in tablets, syrups, and chewable medications to improve palatability.
- Used in oral hygiene products like mouthwashes and toothpastes for a sweet taste without promoting dental caries.
- Cosmetics and Personal Care
- Added to oral care formulations such as toothpaste and mouth rinses for flavor enhancement.
Secondary Uses
- Veterinary Medicine
- Used as a sweetener in animal feed supplements to improve palatability.
- Research
- Studied in food science and nutrition for effects on metabolism and sweetener blends.
1. Basic Identification Attributes
- Chemical Name (IUPAC): Calcium 1,2-benzisothiazol-3(2H)-one-1,1-dioxide salt
- Common/Trade Name: Calcium Saccharin
- CAS Number: 6486-23-3
- HS Code: 2924.29.90
- Molecular Formula: C14H8CaN2O6S2
- Synonyms:
- Calcium saccharin salt
- Saccharin calcium salt
- Calcium saccharinate
2. Physical & Chemical Properties
- Physical State: Crystalline powder
- Color & Odor: White to off-white; odorless
- Melting Point: Approximately 222–225°C (decomposes)
- Density: Approx. 1.75 g/cm³
- Solubility: Soluble in water (about 1.4 g/100 mL at 20°C); insoluble in ethanol
- pH (aqueous solution): Neutral to slightly alkaline (pH 6–8)
- Stability: Stable under normal conditions; heat resistant; stable in acidic and neutral media
3. Safety & Hazard Attributes
- Hazard Class (GHS): Not classified as hazardous; generally recognized as safe (GRAS) for food use
- NFPA Ratings:
- Health: 0
- Flammability: 1
- Reactivity: 0
- Exposure Limits: No specific OSHA/ACGIH limits; avoid dust inhalation
- Toxicity: Low acute toxicity; non-carcinogenic and non-mutagenic according to regulatory authorities
- Reactivity: Chemically stable; avoid strong oxidizers
4. Storage & Handling Attributes
- Storage Conditions: Store in a cool, dry, well-ventilated area away from moisture and incompatible substances
- Container Type: Airtight containers such as plastic or glass bottles or sealed drums
- Shelf Life: Typically 2–3 years under proper storage conditions
- Special Handling: Use PPE to avoid dust exposure; avoid inhalation and skin contact
5. Regulatory & Compliance Attributes
- FDA Status: Approved as a food additive and sweetener (E954) in many countries
- EFSA: Approved for use as a sweetener in the EU with established acceptable daily intake (ADI)
- Transportation: Not classified as hazardous
- Waste Disposal: Dispose according to local non-hazardous waste regulations
6. Environmental & Health Impact
- Ecotoxicity: Low environmental impact; considered biodegradable
- Persistence: Moderate persistence; breaks down in wastewater treatment
- Bioaccumulation: Not expected to bioaccumulate
- Carcinogenicity/Mutagenicity: Not classified as carcinogenic or mutagenic by WHO and FDA
- Biodegradability: Partially biodegradable under aerobic conditions
Safety Handling Precautions
Personal Protective Equipment (PPE):
- Gloves
- Protective goggles
- Dust mask or respirator (when handling powder)
- Protective clothing
Handling Measures:
- Avoid dust formation and inhalation
- Work in well-ventilated areas
- Use local exhaust ventilation if dust is generated
Storage Measures:
- Keep container tightly closed
- Store away from moisture and incompatible substances
- Avoid exposure to direct sunlight and heat
Hygiene Practices:
- Wash hands thoroughly after handling
- Do not eat, drink, or smoke during handling
First Aid Measures
- Inhalation: Move to fresh air; seek medical attention if breathing difficulties occur
- Skin Contact: Wash with soap and water; seek medical attention if irritation develops
- Eye Contact: Rinse thoroughly with water for at least 15 minutes; seek medical advice if irritation persists
- Ingestion: Rinse mouth; seek medical advice if large quantities ingested or symptoms develop
Firefighting Measures
- Fire Hazards: Combustible under fire conditions
- Extinguishing Media: Use water spray, foam, dry chemical, or CO₂ as appropriate for surrounding fire
- Special Precautions: Firefighters should wear full protective gear and self-contained breathing apparatus (SCBA) if necessary
- Decomposition Products: May emit toxic gases such as sulfur oxides and nitrogen oxides under fire conditions
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