Methyl Ethyl Ketoxime ( MEKO)

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Methyl Ethyl Ketoxime (MEKO) is a clear, colorless to pale yellow liquid with a mild, characteristic odor. It is primarily used as a polymerization inhibitor and anti-skinning agent in coatings and paints, preventing premature curing during storage. MEKO is valued for its effectiveness in protecting alkyd and other resin-based coatings and enhancing shelf life.

Description

Primary Uses 

  1. Paints and Coatings

    • Acts as an anti-skinning agent to prevent formation of skin on paint surfaces during storage.

    • Used as a polymerization inhibitor in alkyd, acrylic, and other resin-based coatings.

  2. Adhesives and Sealants

    • Prevents premature curing and gelling during storage.

  3. Chemical Intermediate

    • Used in the manufacture of various chemicals and resins.

Secondary Uses 

  1. Printing Inks

    • Helps stabilize ink formulations by inhibiting unwanted polymerization.

  2. Rubber and Plastics

Acts as a stabilizer in some polymerization processes to control molecular weight and polymer properties.

KEY PRODUCT FEATURES

Key Attributes

Basic Identification Attributes

  • Chemical Name (IUPAC): (E)-N-Hydroxy-1-methylbutan-2-imine

  • Common/Trade Name: Methyl Ethyl Ketoxime (MEKO)

  • CAS Number: 96-29-7

  • HS Code: 2921.42.00

  • Synonyms: MEKO; methyl ethyl ketone oxime; 2-Butanone oxime

Physical & Chemical Properties

  • Physical State: Liquid

  • Color & Odor: Clear to pale yellow; mild characteristic odor

  • Boiling Point: 132°C

  • Melting Point: -38°C

  • Flash Point: 65°C (closed cup)

  • Density: 0.904 g/cm³ at 20°C

  • Solubility: Slightly soluble in water; miscible with most organic solvents

Safety & Hazard Attributes

  • GHS Classification: Flammable liquid, Category 4; Acute toxicity (oral), Category 4; Skin irritation, Category 2

  • Toxicity: Moderate toxicity; avoid ingestion, inhalation, and skin contact

  • Exposure Limits: No widely established limits; follow general chemical safety guidelines

Storage & Handling Attributes

  • Storage Conditions: Store in a cool, well-ventilated place away from heat, sparks, and open flames

  • Container Type: Supplied in sealed metal or plastic containers

  • Shelf Life: Stable under proper storage conditions for up to 2 years

  • Handling Precautions: Use protective gloves and eye protection; avoid inhalation of vapors

 

Regulatory & Compliance Attributes

  • Complies with international chemical safety standards and regulations

  • Registered under relevant chemical inventories (e.g., REACH)

 

Environmental & Health Impact

  • Biodegradability: Biodegradable under suitable conditions

  • Ecotoxicity: Low environmental impact if used as directed

  • Bioaccumulation: Not expected to bioaccumulate

  • Carcinogenicity/Mutagenicity: Not classified as carcinogenic

SAFETY HANDLING PRECAUTIONS

Safety Handling Precautions

  • PPE Required: Chemical-resistant gloves, safety goggles, and protective clothing recommended

  • Handling Guidelines: Use in well-ventilated areas; prevent vapor accumulation

  • Storage Measures: Keep containers tightly closed and stored away from incompatible substances

 

First Aid Measures

  1. Inhalation: Move to fresh air; seek medical attention if respiratory irritation or distress occurs

  2. Skin Contact: Wash thoroughly with soap and water; seek medical advice if irritation develops

  3. Eye Contact: Rinse eyes with plenty of water for at least 15 minutes; seek medical attention if irritation persists

  4. Ingestion: Do not induce vomiting; seek immediate medical assistance

 

Firefighting Measures

  • Fire Hazards: Combustible liquid

  • Extinguishing Media: Use foam, dry chemical, or carbon dioxide extinguishers

  • Special Precautions: Wear full protective equipment and self-contained breathing apparatus

  • Hazardous Combustion Products: May produce nitrogen oxides, carbon oxides, and other toxic gases during fire