Chlorinated Paraffin Wax (CPW)
Chlorinated Paraffin Wax (CPW) is a synthetic chlorinated hydrocarbon obtained by the chlorination of paraffin wax. It typically appears as a waxy solid, ranging from light yellow to dark brown depending on the degree of chlorination and the chain length of the paraffins. CPW is valued for its excellent flame retardant, plasticizing, and extreme pressure (EP) additive properties. It is widely used in industrial applications including metalworking fluids, PVC formulations, rubber compounding, and flame retardant materials. CPW offers thermal stability, chemical resistance, and lubricating qualities, making it a versatile industrial additive.
Chlorinated Paraffin Wax (CPW) Uses
Primary UsesÂ
Industrial & Manufacturing Applications
- Used as a flame retardant additive in paints, coatings, plastics (especially PVC), textiles, and rubber products.
- Acts as an extreme pressure (EP) additive in metalworking fluids and lubricants to reduce wear and friction.
- Serves as a plasticizer and stabilizer in PVC and other polymer formulations, improving flexibility and durability.
- Employed in sealants, adhesives, and caulks to enhance performance and resistance to environmental factors.
Rubber Industry
- Incorporated into rubber compounds to improve processing characteristics, flexibility, and resistance to abrasion.
Secondary UsesÂ
Paints and Coatings
- Used as a secondary plasticizer and pigment dispersant in specialty coatings.
Electrical Industry
- Utilized in cable sheathing and insulation materials for its flame retardant and insulating properties.
Textile Industry
- Applied in textile finishing agents for flame retardancy and durability enhancements.
Leather Industry
Added to leather treatments to improve water resistance and durability.
- Basic Identification Attributes
- Chemical Name (IUPAC): Chlorinated paraffin (complex mixture of polychlorinated n-alkanes)
- Common/Trade Name: Chlorinated Paraffin Wax (CPW)
- CAS Number: 63449-39-8 (varies by chlorination degree)
- HS Code: 2712.90.20
- Molecular Formula: Variable — CnH2n+2-xClx (where n = 10–30+, x = chlorine atoms)
- Synonyms:
- CPW
- Chlorinated paraffin
- Polychlorinated n-alkanes
- Physical & Chemical Properties
- Physical State: Solid wax (flakes, powder, or pastilles)
- Color & Odor: Light yellow to dark brown; mild characteristic odor
- Melting Point: Typically 50–105°C depending on chlorination and chain length
- Boiling Point: Decomposes before boiling
- Density: Approx. 1.3–1.6 g/cm³ depending on chlorination
- Solubility: Insoluble in water; soluble in organic solvents such as chlorinated solvents, aromatic hydrocarbons, and oils
- Chlorine Content: Typically 40–70% by weight, depending on product grade
- Stability: Chemically stable under normal conditions; decomposes at elevated temperatures releasing HCl
- Safety & Hazard Attributes
- Hazard Class (GHS): Classified as hazardous depending on chlorination degree and formulation; may be harmful if inhaled or ingested
- NFPA Ratings:
- Health: 2
- Flammability: 1
- Reactivity: 1
- Exposure Limits: Use with appropriate ventilation; avoid inhalation of dust or fumes
- Toxicity: Possible skin and respiratory irritant; suspected to be persistent organic pollutant (varies by grade)
- Reactivity: Stable but may release toxic gases (HCl) on thermal decomposition
- Storage & Handling Attributes
- Storage Conditions: Store in a cool, dry, well-ventilated area away from heat and ignition sources
- Container Type: Sealed metal drums or fiberboard containers lined with inert materials
- Shelf Life: Up to 3 years if stored properly
- Special Handling: Use PPE including gloves, goggles, and dust masks; avoid dust generation
- Regulatory & Compliance Attributes
- REACH Status: Subject to restrictions due to environmental and health concerns (varies by chlorine content)
- Transportation: Classified as non-dangerous goods but subject to local regulations
- Waste Disposal: Dispose as hazardous waste in compliance with local regulations; avoid environmental release
- Environmental Restrictions: Some chlorinated paraffins are restricted or banned in certain regions (e.g., EU) due to persistence and bioaccumulation
- Environmental & Health Impact
- Ecotoxicity: Persistent and bioaccumulative; toxic to aquatic organisms
- Persistence: Very persistent in the environment
- Bioaccumulation: High potential for bioaccumulation in aquatic organisms
- Carcinogenicity/Mutagenicity: Some grades are suspected carcinogens; regulatory agencies recommend caution
Biodegradability: Poorly biodegradable
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Safety Handling Precautions
- PPE: Protective gloves, safety goggles, and respiratory protection if dust or fumes are present
- Handling: Avoid inhalation of dust or vapors; use local exhaust ventilation
- Storage: Keep containers tightly closed; store away from incompatible substances such as strong oxidizers
- Hygiene: Wash hands thoroughly after handling; do not eat, drink, or smoke during use
First Aid Measures
- Inhalation: Move affected person to fresh air; seek medical attention if breathing difficulties develop
- Skin Contact: Wash thoroughly with soap and water; seek medical attention if irritation persists
- Eye Contact: Rinse cautiously with water for 15 minutes; seek medical attention if irritation persists
- Ingestion: Do not induce vomiting; seek immediate medical attention
Firefighting Measures
- Fire Hazards: Combustible; may release toxic gases including HCl when burned
- Extinguishing Media: Use foam, dry chemical, or COâ‚‚; avoid water jets
- Special Precautions: Firefighters should wear full protective gear and self-contained breathing apparatus
Decomposition Products: Hydrogen chloride, carbon monoxide, and other toxic fumes