Understanding Oxalic Acid Extra Pure: Properties, Applications, And Safety
Oxalic Acid Extra Pure is a high-purity crystalline organic compound that plays a significant role in various laboratory, industrial, and even domestic applications. With the chemical formula C₂H₂O₄·2H₂O (in its most common dihydrate form), oxalic acid is known for its strong acidic nature and powerful chelating ability—particularly for metal ions like calcium and iron.
This blog aims to delve into the essential characteristics, applications, safety concerns, and handling guidelines of Oxalic Acid Extra Pure, helping students, researchers, technicians, and chemical buyers understand its full potential and proper use.
What is Oxalic Acid Extra Pure?
Oxalic acid is a naturally occurring compound found in many plants, such as spinach, rhubarb, and beetroot. In its extra pure laboratory-grade form, it is highly refined and free from significant impurities, making it suitable for analytical chemistry, synthesis, and pharmaceutical testing.
In appearance, it is a white crystalline solid that dissolves easily in water, forming a colorless, acidic solution. It has a slightly sour taste and is odorless in solid form.
Key Physical & Chemical Properties:
- Chemical Formula: C₂H₂O₄·2H₂O (dihydrate)
- Molecular Weight: 126.07 g/mol
- Melting Point: 101–102 °C (dihydrate loses water)
- Solubility: Highly soluble in water and alcohol
- Acidity: A strong organic acid with two replaceable hydrogen atoms
These characteristics make it a versatile compound that reacts with various bases and metal ions, making it particularly useful in titration procedures and surface cleaning applications.
Common Applications of Oxalic Acid Extra Pure
1. Analytical Reagent in Laboratories
In chemistry labs, oxalic acid is frequently used as a primary standard for titrations involving strong bases like sodium hydroxide. Its high purity and stable crystalline structure make it ideal for accurate standardization procedures.
2. Metal Cleaning and Rust Removal
Due to its strong chelating properties, oxalic acid is a preferred agent for cleaning metal surfaces and removing rust stains. It reacts with iron oxides to form soluble iron oxalates that can be rinsed away.
3. Textile and Leather Industry
Oxalic acid serves as a bleaching agent in textile processing, where it helps remove stains and iron deposits. It is also used in the tanning of leather, helping achieve specific surface finishes.
4. Pharmaceutical and Food Analysis
In its extra pure form, oxalic acid is sometimes employed in the pharmaceutical industry for pH adjustment, analytical control, and precipitation reactions. It is not added directly to foods but is important in the analysis of oxalate levels in raw materials.
5. Wood Bleaching and Restoration
Oxalic acid is used in woodworking and restoration to bleach and brighten wood, especially in cases where water damage or iron staining has occurred.
Safety and Handling
While useful, oxalic acid poses several hazards if not handled properly. It is toxic if ingested in large quantities and can cause irritation or burns to the skin, eyes, and respiratory system.
Safety Guidelines:
- PPE: Always wear gloves, goggles, and a lab coat when handling oxalic acid.
- Ventilation: Use in a well-ventilated area or fume hood to avoid inhaling vapors or dust.
- Storage: Store in tightly sealed containers away from heat and incompatible materials such as strong oxidizers or bases.
- First Aid:
- Inhalation: Move to fresh air; seek medical help if irritation persists.
- Contact: Wash skin or eyes with plenty of water for at least 15 minutes.
- Ingestion: Seek immediate medical attention; do not induce vomiting.
- Inhalation: Move to fresh air; seek medical help if irritation persists.
Environmental Impact
Oxalic acid is biodegradable and breaks down into carbon dioxide and water. However, due to its toxicity in concentrated form, disposal must be done in compliance with local chemical waste management regulations to avoid groundwater contamination.
Final Thoughts
Oxalic Acid Extra Pure is more than just a chemical—it’s a tool that supports essential processes in chemistry, industry, and restoration work. Whether you’re standardizing a solution in the lab or restoring an antique wooden table, oxalic acid’s unique properties make it a reliable and powerful compound. But with that power comes responsibility, and safe handling practices are non-negotiable.
If you’re sourcing oxalic acid for laboratory or industrial use, ensure you obtain the Extra Pure grade to guarantee performance, reliability, and minimal impurities.

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