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Ammonia Acetate
Original price was: $700.00.$600.00Current price is: $600.00.
Ammonium Ferrous Sulphate 500gm
Original price was: $2,500.00.$2,300.00Current price is: $2,300.00.
Ammonium Cupric Chloride
Original price was: $2,500.00.$2,300.00Current price is: $2,300.00.
Ammonium cupric chloride is a chemical compound composed of copper(II) (Cu²⁺), ammonium (NH₄⁺), and chloride (Cl⁻) ions. It appears as a greenish or yellowish crystalline solid, depending on its hydration state and structure.
Majorly, ammonium cupric chloride is used in research and specialized industrial applications. It serves as a catalyst in organic synthesis, where copper(II) facilitates oxidation or coupling reactions. In electroplating, it can act as a copper ion source for depositing thin metallic layers.
Description
Ammonium Cupric Chloride Uses
Catalyst
- Used as a catalyst or precursor in organic synthesis and chemical reactions, particularly where copper(II) (Cu²⁺) plays a role in redox or coordination processes
Electroplating & Metal Finishing
- May serve as a source of copper ions in specialized electroplating baths for depositing copper coatings on surfaces.
Chemical Research
- Studied in coordination chemistry due to its interesting structure (tetrachlorocuprate(II) complex, [CuCl₄]²⁻).
- Used to investigate magnetic properties, as some copper(II) complexes exhibit interesting spin states.
Educational Demonstrations
- Sometimes used in chemistry labs to demonstrate ligand field theory and the behavior of transition metal complexes.
Material Science
- Investigated for potential use in hybrid perovskite materials or as a precursor for copper-containing thin films in electronics.
Analytical Chemistry
- May act as a reagent in qualitative or quantitative analysis for detecting specific anions or cations.
Photography (Historical Use)
- Some copper-based ammonium chloride complexes were historically explored in photographic processes, though not widely adopted.
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KEY ATTRIBUTES
1. Basic Identification Attributes
- Chemical Name: Tetraamminecopper(II) chloride (IUPAC), Ammonium cupric chloride (common)
- CAS Number: 13426-91-0 (for tetraamminecopper(II) chloride)
- HS Code: 2827.39.90 (likely, varies by jurisdiction)
- Molecular Formula: [Cu(NH₃)₄]Cl₂ or CuCl₂·4NH₃
- Synonyms:
- Cupric ammonium chloride
- Tetraamminecopper dichloride
- Copper(II) ammonium chloride
2. Physical & Chemical Properties
- Physical State: Solid (crystalline powder)
- Color & Odor: Deep blue crystals; faint ammonia odor (if hydrated or decomposing).
- Boiling Point: Decomposes before boiling (releases NH₃).
- Melting Point: ~100–150°C (decomposes).
- Density/Specific Gravity: ~1.6–1.8 g/cm³ (estimated).
- Solubility:
- Soluble in water (forms deep blue solution).
- Insoluble in non-polar solvents (e.g., ether).
- pH Level: Slightly acidic to neutral (depends on hydration).
- Vapor Pressure: Low (but releases NH₃ gas if heated).
- Flash Point: Not flammable (but releases toxic NH₃ fumes when heated).
- Autoignition Temperature: N/A (non-flammable).
- Viscosity: N/A (solid).
3. Safety & Hazard Attributes
- Hazard Class (GHS):
- Acute Toxicity(Oral, Inhalation: Category 4).
- Skin/Irritation: May cause irritation (Category 2).
- Hazardous Decomposition Products: NH₃ gas, Cl₂ (if heated strongly).
- NFPA Ratings:
- Health: 2| Flammability: 0 | Reactivity: 1.
- Exposure Limits:
- NH₃ (from decomposition): OSHA PEL = 50 ppm (8-hr TWA).
- Copper Dust: OSHA PEL = 1 mg/m³ (as Cu).
- Reactivity:
- Incompatible with strong acids (releases NH₃), oxidizers.
- Stable under normal conditions but decomposes with heat.
4. Storage & Handling Attributes
- Storage Conditions:
- Cool, dry, well-ventilated area.
- Away from acids and moisture.
- Incompatible Materials:
- Strong acids (e.g., H₂SO₄, HCl), oxidizers (e.g., KMnO₄).
- Container Type:
- Airtight plastic or glass (avoid metal due to corrosion risk).
- Shelf Life: ~1–2 years if sealed properly.
- Special Handling:
- Use gloves (nitrile) and goggles.
- Fume hood if heating (due to NH₃ risk).
5. Regulatory & Compliance Attributes
- Regulatory Status:
- EPA: Not listed as hazardous waste (but copper compounds are regulated).
- REACH: Registered for industrial use.
- DOT: Non-hazardous for transport (unless mixed with other chemicals).
- Hazard Symbols (GHS):
- Exclamation Mark(irritant).
- Health Hazard(if decomposed).
- Transportation Restrictions:
- UN Number: None (unless mixed).
- Waste Disposal:
- Treat as heavy metal waste (EPA/RCRA for copper content).
6. Environmental & Health Impact
- Ecotoxicity:
- Toxic to aquatic life (copper ions: LC50 for fish ~0.1–1 mg/L).
- Persistence:
- Copper persists in sediments; NH₃ degrades rapidly.
- Carcinogenicity:
- Not classified by IARC/NTP (but copper dust may cause lung irritation).
- Biodegradability:
- NH₄⁺ ions degrade; Cu²⁺ accumulates in ecosystems
SAFETY PRECAUTIONS
Personal Protection:
- Gloves:Wear chemical-resistant gloves (nitrile or neoprene).
- Eye Protection:Use safety goggles or a face shield.
- Respiratory Protection:Use a NIOSH-approved respirator (N95 or higher) if dust or fumes are present.
- Clothing:Wear a lab coat or chemical-resistant apron to prevent skin contact.
Handling & Storage:
- Ventilation:Work in a well-ventilated area or use a fume hood.
- Avoid Contact:Prevent skin, eye, and inhalation exposure.
- Storage:Keep in a tightly sealed container in a cool, dry place away from incompatible substances (e.g., strong acids, alkalis, and reducing agents).
- Hygiene:Wash hands thoroughly after handling.
Incompatibilities:
- Avoid contact with strong acids, bases, and reducing agents(may release toxic gases like ammonia or chlorine).
Inhalation (Breathing in Dust/Fumes):
- Move to fresh air immediately.
- If breathing is difficult, administer oxygen.
- Seek medical attention if symptoms persist.
Skin Contact:
- Remove contaminated clothing.
- Wash affected area with plenty of water and soap for at least 15 minutes.
- Seek medical attention if irritation or burns occur.
Eye Contact:
- Rinse eyes immediately with lukewarm water for at least 15 minutes, holding eyelids open.
- Seek immediate medical attention.
Ingestion (Swallowing):
- Do NOT induce vomiting.
- Rinse mouth with water and drink small amounts of water if conscious.
- Seek immediate medical attention.
Fire Hazards:
- Ammonium cupric chloride itself is not flammable, but it may decompose at high temperatures, releasing toxic fumes (ammonia, chlorine, nitrogen oxides).
Suitable Extinguishing Media:
- Use water spray, dry chemical powder, CO₂, or foamfor surrounding fires.
- Do not use water jets(may spread contaminated runoff).
Protection for Firefighters:
- Wear self-contained breathing apparatus (SCBA)and full protective gear.
- Prevent runoff from entering drains or water sources.
Special Considerations:
- Toxic fumes may form in fire conditions—evacuate unnecessary personnel.
- Cool containers exposed to fire with water spray to prevent rupture.
Spill & Leak Response:
- Small Spills:Absorb with inert material (sand, vermiculite) and dispose of properly.
- Large Spills:Evacuate area, wear PPE, and contain spill to prevent environmental contamination.
Disposal:
- Follow local regulations for hazardous waste disposal.
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