Calcium Hypochlorite (Chlorine)

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Calcium Hypochlorite (Ca(ClO)â‚‚) is a white to slightly yellow crystalline powder or granules known for its strong oxidizing and disinfectant properties. The 65% grade indicates the available chlorine content, making it a powerful bleaching, sanitizing, and oxidizing agent. It is commonly used for water treatment, sanitation, and as a bleaching agent in industrial and household applications. Calcium Hypochlorite dissolves in water to release hypochlorous acid, which effectively kills bacteria, viruses, and fungi.

Description

Primary Uses 

  1. Water Treatment & Disinfection 
    • Widely used to disinfect drinking water and swimming pools by killing harmful microorganisms. 
    • Used in wastewater treatment to oxidize contaminants and reduce pathogens. 
  2. Sanitation & Hygiene 
    • Applied for sanitizing surfaces in hospitals, food processing plants, and public facilities. 
    • Used for deodorizing and controlling microbial growth in sewage systems. 
  3. Industrial & Household Bleaching 
    • Acts as a bleaching agent for textiles, paper pulp, and other materials. 
    • Commonly used in household disinfectants and cleaners. 
  4. Agriculture 
    • Used to sanitize irrigation water and disinfect equipment. 

Secondary Uses 

  1. Odor Control 
    • Employed in waste management to reduce odors by oxidizing odor-causing compounds. 
  2. Chemical Manufacturing 
    • Used as an oxidizing agent in various chemical synthesis processes. 
  3. Food Industry 
    • Occasionally used for washing and disinfecting fruits, vegetables, and food-contact surfaces (regulated use). 

 

PRODUCT KEY FEATURES

Basic Identification Attributes

  • Chemical Name (IUPAC): Calcium hypochlorite 
  • Common/Trade Name: Calcium Hypochlorite 65%, Bleaching Powder, Chlorinated Lime 
  • CAS Number: 7778-54-3 
  • HS Code: 2828.10.00 
  • Molecular Formula: Ca(ClO)â‚‚ 
  • Synonyms: 
    • Bleaching powder 
    • Chlorinated lime 
    • Calcium oxychloride 
    • Hypochlorous acid calcium salt 

2. Physical & Chemical Properties

  • Physical State: Granular or powder 
  • Color & Odor: White to pale yellow; strong chlorine odor 
  • Melting Point: Decomposes at ~100°C releasing chlorine gas 
  • Boiling Point: Not applicable (decomposes) 
  • Density: Approx. 2.4 g/cm³ 
  • Solubility: Soluble in water releasing hypochlorous acid and calcium hydroxide 
  • pH: Strongly alkaline (around pH 11–12 in solution) 
  • Stability: Sensitive to moisture, heat, and sunlight; decomposes releasing chlorine gas 

3. Safety & Hazard Attributes

  • Hazard Class (GHS): Oxidizer, corrosive, irritant 
  • NFPA Ratings: 
    • Health: 3 
    • Flammability: 0 
    • Reactivity: 3 
  • Exposure Limits: No specific OSHA limits; avoid inhalation of dust and fumes 
  • Toxicity: Toxic by ingestion and inhalation; causes severe skin and eye burns 
  • Reactivity: Reacts violently with acids, organic materials, and reducing agents; releases chlorine gas 

4. Storage & Handling Attributes

  • Storage Conditions: Store in a cool, dry, well-ventilated area away from incompatible materials (acids, organic substances) 
  • Container Type: Sealed, moisture-proof containers (polyethylene drums, lined steel containers) 
  • Shelf Life: Typically 6–12 months if stored properly in dry conditions 
  • Special Handling: Use PPE; avoid moisture contact and dust generation; store away from heat and sunlight 

5. Regulatory & Compliance Attributes

  • FDA Status: Approved for use in water disinfection (regulated levels) 
  • Transportation: Classified as an oxidizing solid (UN 2880 or UN 2014 depending on form) 
  • Waste Disposal: Dispose according to hazardous chemical waste regulations; neutralize before disposal 

6. Environmental & Health Impact

  • Ecotoxicity: Highly toxic to aquatic life; avoid environmental release 
  • Persistence: Decomposes releasing chlorine and calcium salts 
  • Bioaccumulation: Not expected to bioaccumulate 
  • Carcinogenicity/Mutagenicity: Not classified as carcinogenic or mutagenic 
  • Biodegradability: Not biodegradable; decomposes chemically 
SAFETY HANDLING PRECAUTIONS

Personal Protective Equipment (PPE):

  • Chemical-resistant gloves 
  • Safety goggles or face shield 
  • Respirator or dust mask (for dust/fume) 
  • Protective clothing 

Handling Measures:

  • Avoid inhalation, ingestion, and skin or eye contact 
  • Handle in well-ventilated areas 
  • Avoid contact with moisture, acids, and organic materials 

Storage Measures:

  • Keep containers tightly sealed and dry 
  • Store away from incompatible materials and sources of heat 

Hygiene Practices:

  • Wash hands and exposed skin thoroughly after handling 
  • Do not eat, drink, or smoke while handling the chemical 

 

First Aid Measures

  • Inhalation: Move to fresh air immediately; seek medical attention if breathing difficulties occur 
  • Skin Contact: Rinse with plenty of water for at least 15 minutes; remove contaminated clothing; seek medical attention 
  • Eye Contact: Flush eyes with water for at least 15 minutes; seek urgent medical care 
  • Ingestion: Do not induce vomiting; rinse mouth and seek immediate medical attention 

 

Firefighting Measures

  • Fire Hazards: Non-flammable but strong oxidizer; may intensify fire of combustible materials 
  • Extinguishing Media: Use water spray, fog, or foam; do NOT use dry chemical or COâ‚‚ alone 
  • Special Precautions: Firefighters should wear full protective gear and SCBA 
  • Decomposition Products: May release toxic chlorine gas and calcium oxides under fire conditions