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Acticide
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Acticide is a brand name for a range of biocides and preservatives used primarily in industrial and commercial products to prevent the growth of bacteria, fungi, algae, and other microorganisms. It is commonly added to paints, coatings, adhesives, plastics, and personal care products to extend their shelf life and maintain product quality.
Description
Primary Uses
1. Water Treatment & Cooling Systems
- Prevents biofilm formation in cooling towers, pipelines, and industrial water systems.
- Controls Legionella, Pseudomonas, and other harmful bacteria.
2. Paints & Coatings
- Used as a in-can preservative to extend shelf life of water-based paints, adhesives, and emulsions.
- Prevents fungal/algal growth in wet-state paints and dry film coatings.
3. Personal Care & Cosmetics
- Preserves shampoos, lotions, creams against microbial contamination (e.g., Acticide® MBS).
- Extends product lifespan without affecting fragrance or texture.
4. Leather & Textile Industry
- Prevents mold and bacterial degradation in wet leather processing and stored textiles.
5. Fuel & Lubricant Preservation
- Used in diesel, biofuels, and metalworking fluids to inhibit microbial spoilage.
Secondary Uses
- Pulp & Paper Industry – Controls slime-forming bacteria in paper mills.
- Agriculture – Preserves liquid fertilizers and pesticide formulations.
- HVAC Systems – Disinfects air washers and humidifiers.
- Household Cleaners – Added to detergents for antimicrobial action.
PRODUCT KEY ATTRIBUTES
1. Basic Identification Attributes
- Chemical Name:
- For Acticide MBS: Blend of 2-Methylisothiazol-3(2H)-one (MIT) and 1,2-Benzisothiazol-3(2H)-one (BIT)
- For Acticide SPX: Polyhexamethylene biguanide hydrochloride (PHMB)
- Common/Trade Names:
- Acticide MBS
- Acticide SPX
- Acticide EPW (varies by specific product)
- CAS Numbers:
- MIT: [2682-20-4]
- BIT: [2634-33-5]
- PHMB: [32289-58-0]
- HS Code: 3808.94.90 (other biocides)
- Molecular Formula:
- MIT: C₄H₅NOS
- BIT: C₇H₅NOS
- PHMB: (C₈H₁₇N₅)ₙ·HCl
- Synonyms:
- Isothiazolinone blend
- PHMB solution
- Microbiocide
2. Physical & Chemical Properties (for Acticide MBS typical formulation)
- Physical State: Clear to slightly yellow liquid
- Color & Odor: Pale yellow; mild characteristic odor
- Melting Point: <-20°C
- Boiling Point: ~100°C (water base)
- Density: 1.02-1.08 g/cm³ at 20°C
- Solubility:
- Water: Fully miscible
- Organic solvents: Partially soluble
- pH Level: 2.5-5.0 (acidic)
- Vapor Pressure: ~23 hPa at 20°C (water dominated)
- Flash Point: >100°C (non-flammable)
- Active Content: 1.5-50% (varies by product)
3. Safety & Hazard Attributes
- Hazard Class (GHS):
- Skin Corrosion/Irritation (Category 1B)
- Eye Damage (Category 1)
- Acute Toxicity (Oral, Category 4)
- Hazardous to Aquatic Life (Chronic 1)
- NFPA Ratings:
- Health: 2
- Flammability: 0
- Reactivity: 0
- Exposure Limits:
- MIT/BIT: 0.5 mg/m³ (8h TWA)
- PHMB: 1 mg/m³ (total dust)
- Reactivity:
- Incompatible with strong oxidizers
- Avoid alkaline conditions (pH >9)
4. Storage & Handling Attributes
- Storage Conditions:
- 5-30°C in original container
- Protect from freezing
- Keep tightly closed
- Incompatible Materials:
- Strong bases
- Reducing agents
- Container Type:
- HDPE or stainless steel
- Avoid carbon steel
- Shelf Life: 12-24 months unopened
- Special Handling:
- Chemical-resistant gloves (nitrile)
- Face shield
- Fume hood for large volumes
5. Regulatory & Compliance Attributes
- Regulatory Status:
- EPA Registered (USA)
- BPR Approved (EU)
- K-BPR (Korea)
- Hazard Symbols (GHS):
- Corrosion
- Aquatic toxicity
- Exclamation mark
- Transportation Restrictions:
- UN number: 3082 (for some formulations)
- Packing Group: III
- Waste Disposal:
- Licensed hazardous waste facility
- Never dispose to drains
6. Environmental & Health Impact
- Ecotoxicity:
- LC50 (fish): 0.1-10 mg/L
- EC50 (daphnia): 0.01-1 mg/L
- Persistence:
- MIT/BIT: 10-30 days half-life in water
- PHMB: 5-15 days half-life
- Carcinogenicity:
- Not classified (IARC/NTP)
- Biodegradability:
- MIT/BIT: <20% in 28 days
- PHMB: <10% in 28 days
SAFETY HANDLING
- Safety handling
Personal Protective Equipment (PPE):
- Gloves: Nitrile or neoprene (check compatibility with specific formulation)
- Eye Protection: Chemical splash goggles + face shield
- Respiratory: NIOSH-approved N95 (for dust) or organic vapor respirator (for aerosols)
- Body: Chemical-resistant coveralls + impermeable apron
Handling & Storage:
- Use in well-ventilated areas or under fume hoods
- Ground and bond containers to prevent static discharge
- Store in original, labeled containers away from heat, sunlight, and incompatible chemicals (e.g., strong oxidizers, acids)
- Keep at 15–25°C (avoid freezing or extreme heat)
Hygiene & Work Practices:
- No eating, drinking, or smoking in handling areas
- Wash hands thoroughly after use
- Emergency eyewash/shower stations must be accessible
2. First Aid Measures
Skin Contact:
- Remove contaminated clothing immediately
- Wash with soap and lukewarm water for ≥15 minutes
- Seek medical attention if irritation or burns develop
Eye Contact:
- Rinse eyes continuously with water for ≥20 minutes (hold eyelids open)
- Seek immediate medical attention (risk of corneal damage)
Inhalation:
- Move to fresh air immediately
- Administer oxygen if breathing is difficult
- Call poison control or emergency services if symptoms persist
Ingestion:
- Do NOT induce vomiting
- Rinse mouth with water
- Seek emergency medical care
3. Firefighting Measures
Fire Hazards:
- Combustible (depending on formulation)
- May release toxic fumes (HCl, CO, NOx, formaldehyde) when heated
Extinguishing Media:
✔ Alcohol-resistant foam
✔ CO₂
✔ Dry chemical powder
✖ Avoid water jets (may spread burning liquid)
Firefighting Protocol:
- Wear SCBA (self-contained breathing apparatus) + full protective gear
- Cool nearby containers with water spray
- Contain runoff to prevent environmental contamination
4. Spill & Leak Management
Small Spills (<1L):
- Wear full PPE
- Absorb with inert material (vermiculite, sand, or spill pads)
- Place in sealed hazardous waste container
Large Spills (>1L):
- Evacuate area
- Contain spill with barriers (clay, sandbags)
- Prevent entry into drains or waterways
- Call HAZMAT team if necessary
Disposal:
- Treat as hazardous waste (follow local regulations)
- Do not pour down drains
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