Manganese Sulphate Monohydrate

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 Manganese Sulphate Monohydrate is an inorganic chemical compound with the formula MnSO₄·H₂O. It appears as a pale pink crystalline powder and is highly soluble in water. It is primarily used as a source of manganese, an essential micronutrient, in fertilizers, animal feed, and industrial processes. This monohydrate form is the most stable and commonly used in agriculture and feed-grade applications. It also finds use in various chemical syntheses, electroplating, and as a reagent in laboratories.

Description

Manganese Sulphate Monohydrate

Primary Uses

  1. Agriculture and Fertilizer Industry

  • Micronutrient Fertilizer: Used as a manganese supplement in soil to correct manganese deficiency in crops like cereals, fruits, vegetables, and legumes.
  • Foliar Spray and Soil Application: Applied directly to plants or soil to improve photosynthesis, chlorophyll production, and enzyme activation.
  • Component in NPK Blends: Included in multi-nutrient formulations for balanced crop nutrition.
  1. Animal Feed Industry

  • Feed Additive: Serves as a manganese supplement in poultry, swine, cattle, and aquaculture feed to support bone development, enzyme function, and reproductive health.
  • Premix Formulations: Used in vitamin-mineral premixes for livestock and pets.
  1. Chemical Industry

  • Intermediate in Manganese Compound Production: Used in the manufacture of other manganese-based chemicals (e.g., manganese dioxide, manganese carbonate).
  • Electroplating: Employed as an additive in electroplating baths for depositing manganese coatings.
  1. Battery Industry

  • Raw Material in Battery Manufacturing: Used in the production of manganese dioxide for dry cell batteries (particularly alkaline and zinc-carbon batteries).

 

Secondary Uses

  1. Water Treatment

  • Trace Element Supplementation: Occasionally used in treating drinking or industrial water where manganese is deficient or as part of a micronutrient mix.
  1. Laboratory Applications

  • Analytical Reagent: Used in lab reagents and tests, including redox titrations and preparation of analytical manganese solutions.
  1. Textile and Dyeing Industry

  • Catalyst/Modifier: Used in dyeing processes and textile treatments as a mordant or chemical modifier.
  1. Pharmaceuticals and Nutraceuticals

  • Nutrient Source: May be used in trace amounts in vitamin or mineral formulations, although less common than food-grade alternatives.
PRODUCT KEY FEATURES
  1. Basic Identification Attributes
  • Chemical Name (IUPAC): Manganese(II) sulfate monohydrate
  • Common/Trade Name: Manganese Sulphate Monohydrate
  • CAS Number: 10034-96-5
  • HS Code: 2833.29.30
  • Synonyms: Manganous sulfate monohydrate; MnSO₄·H₂O; Pink salt of manganese; Manganese(II) sulfate hydrate

 

  1. Physical & Chemical Properties
  • Physical State: Crystalline solid
  • Color & Odor: Pale pink; odorless
  • Molecular Formula: MnSO₄·H₂O
  • Molecular Weight: 169.02 g/mol
  • Solubility: Highly soluble in water; insoluble in ethanol
  • Density: ~2.95 g/cm³
  • Melting Point: Decomposes at ~850 °C
  • pH (5% Solution): ~4.0 – 6.0
  • Stability: Stable under normal conditions

 

  1. Safety & Hazard Attributes
  • GHS Classification:
    • Acute toxicity (oral) – Category 4
    • Eye irritation – Category 2A
    • Harmful to aquatic life – Category 2
  • Toxicity:
    • Harmful if swallowed in large quantities
    • May cause irritation to eyes and respiratory tract
  • Exposure Limits:
    • ACGIH TLV (as Mn): 0.1 mg/m³ (inhalable)
    • OSHA PEL (total Mn dust): 5 mg/m³ (ceiling limit)

 

  1. Storage & Handling Attributes
  • Storage Conditions:
    • Store in a cool, dry, well-ventilated place
    • Protect from moisture, as it may cake or dissolve
  • Container Type:
    • Packed in woven bags, drums, or HDPE-lined sacks
  • Shelf Life:
    • 2–3 years if stored in sealed packaging
  • Handling Precautions:
    • Avoid dust formation
    • Use appropriate PPE (gloves, goggles, dust mask)

 

  1. Regulatory & Compliance Attributes
  • Compliance:
    • Approved for use in agriculture and feed industries (FAO/WHO, AAFCO)
    • REACH-registered and listed on TSCA inventory
    • Must comply with heavy metal limits in food and feed use
  • Labeling Requirements:
    • Include hazard symbols for health and environmental risks
    • State manganese content clearly for agricultural use

 

  1. Environmental & Health Impact
  • Biodegradability: Not applicable (inorganic compound)
  • Ecotoxicity: Harmful to aquatic organisms at high concentrations
  • Bioaccumulation: Not significant
  • Carcinogenicity/Mutagenicity: Not classified as carcinogenic
  • Soil Impact: Beneficial in appropriate doses; excess may inhibit other micronutrient uptake
SAFETY HANDLING PRECAUTIONS
  1. Safety Handling Precautions
  • PPE Required:
    • Dust mask or respirator
    • Safety goggles
    • Protective gloves and clothing
  • Handling Guidelines:
    • Minimize dust generation
    • Wash hands thoroughly after handling
  • Storage Measures:
    • Keep containers sealed and labeled
    • Avoid contamination with food or feed not intended for fortification

 

  1. First Aid Measures
  • Inhalation: Move to fresh air; seek medical attention if irritation persists
  • Skin Contact: Wash thoroughly with soap and water
  • Eye Contact: Rinse immediately with water for at least 15 minutes
  • Ingestion: Rinse mouth; seek medical advice if large amounts are ingested

 

  1. Firefighting Measures
  • Fire Hazards: Non-flammable
  • Extinguishing Media: Use media suitable for surrounding materials (water, foam, dry chemical)
  • Special Precautions: Avoid inhaling dust or fumes
  • Hazardous Combustion Products: May release sulfur oxides and manganese oxides when decomposed at high temperatures