Manganous Dihydrogen Phosphate

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 Manganous Dihydrogen Phosphate is an inorganic manganese compound with the formula Mn(H₂PO₄)₂. It is typically encountered as a hydrated crystalline solid that is soluble in water. This compound serves as a valuable source of manganese and phosphorus in agricultural and industrial applications. It is primarily used as a micronutrient fertilizer component, an additive in animal feed, and a reagent in chemical syntheses. Its high solubility makes it effective for foliar sprays and soil applications to correct manganese deficiencies in crops.

Description

Manganous Dihydrogen Phosphate

Primary Uses

  1. Agriculture and Fertilizer Industry

  • Micronutrient Fertilizer: Supplies manganese and phosphorus essential for plant growth, enhancing photosynthesis, enzyme activation, and energy transfer.
  • Foliar and Soil Application: Used in foliar sprays or soil amendments to correct manganese deficiency in a wide range of crops including cereals, fruits, and vegetables.
  • Component in Blended Fertilizers: Incorporated into complex NPK blends to provide balanced micronutrient nutrition.
  1. Animal Feed Industry

  • Feed Additive: Provides manganese supplementation for livestock and poultry to support metabolic functions, bone development, and reproductive health.
  • Premix Ingredient: Used in vitamin-mineral premixes for improved bioavailability of manganese.
  1. Chemical and Industrial Applications

  • Reagent in Chemical Synthesis: Utilized in laboratories and industry for synthesizing manganese-containing compounds.
  • Electroplating and Coatings: Employed in some specialized plating and coating formulations involving manganese.

 

Secondary Uses

  1. Water Treatment

  • Occasionally used as a micronutrient supplement in water treatment processes where manganese levels are deficient.
  1. Pharmaceutical and Nutraceutical Industry

  • Utilized in trace amounts in supplements and formulations requiring manganese and phosphate.
  1. Research and Laboratory Use

  • Used as a standard reagent or reference material in analytical chemistry and material science research.
PRODUCT KEY FEATURES
  1. Basic Identification Attributes
  • Chemical Name (IUPAC): Manganese(II) dihydrogen phosphate
  • Common/Trade Name: Manganous Dihydrogen Phosphate
  • CAS Number: 13446-38-7
  • HS Code: 2835.39.90
  • Synonyms: Manganese dihydrogen phosphate; Mn(Hâ‚‚POâ‚„)â‚‚; Manganese phosphate monobasic

 

  1. Physical & Chemical Properties
  • Physical State: Crystalline solid
  • Color & Odor: Pale pink to light purple; odorless
  • Molecular Formula: Mn(Hâ‚‚POâ‚„)â‚‚
  • Molecular Weight: Approximately 178.91 g/mol (anhydrous)
  • Solubility: Highly soluble in water
  • Density: ~2.4 g/cm³ (varies with hydration)
  • Melting Point: Decomposes before melting
  • pH (5% solution): Acidic, typically 2.5 – 3.5
  • Stability: Stable under normal storage conditions

 

  1. Safety & Hazard Attributes
  • GHS Classification:
    • Eye irritation (Category 2A)
    • Skin irritation (Category 2)
    • Harmful if swallowed (Category 4)
  • Toxicity:
    • May cause irritation to eyes, skin, and respiratory tract
    • Harmful if ingested in large quantities
  • Exposure Limits:
    • No specific occupational exposure limits, standard dust precautions recommended

 

  1. Storage & Handling Attributes
  • Storage Conditions:
    • Store in a cool, dry, well-ventilated area away from moisture
  • Container Type:
    • Packed in sealed plastic or fiber drums or bags with moisture barriers
  • Shelf Life:
    • 2 years when stored properly
  • Handling Precautions:
    • Avoid dust generation
    • Use appropriate PPE such as gloves, goggles, and dust masks

 

  1. Regulatory & Compliance Attributes
  • Compliance:
    • Meets agricultural and feed additive regulations where applicable
    • Registered under relevant chemical safety guidelines (e.g., REACH)
  • Labeling Requirements:
    • Must include hazard statements regarding irritation and ingestion risks

 

  1. Environmental & Health Impact
  • Biodegradability: Not applicable (inorganic compound)
  • Ecotoxicity: Low to moderate; avoid release in high concentrations to aquatic systems
  • Bioaccumulation: Not expected to bioaccumulate
  • Carcinogenicity/Mutagenicity: Not classified as carcinogenic
SAFETY HANDLING PRECAUTIONS
  1. Safety Handling Precautions
  • PPE Required:
    • Dust mask or respirator
    • Protective gloves and goggles
  • Handling Guidelines:
    • Minimize dust exposure
    • Work in well-ventilated areas
  • Storage Measures:
    • Keep containers tightly closed and dry
    • Store away from incompatible materials like strong bases or oxidizers

 

  1. First Aid Measures
  • Inhalation: Move affected person to fresh air; seek medical attention if symptoms persist
  • Skin Contact: Wash with soap and water; seek medical advice if irritation occurs
  • Eye Contact: Rinse thoroughly with water for 15 minutes; consult a physician if irritation persists
  • Ingestion: Rinse mouth; do not induce vomiting; seek immediate medical assistance

 

  1. Firefighting Measures
  • Fire Hazards: Non-flammable
  • Extinguishing Media: Use water spray, foam, or dry chemical extinguishers for surrounding fires
  • Special Precautions: Avoid inhalation of dust or decomposition products
  • Hazardous Combustion Products: May release phosphorus oxides and manganese oxides upon decomposition at high temperatures