Ammonium Cupric Chloride
Ammonium Cupric Chloride is a blue-green crystalline inorganic compound composed of copper, ammonium, and chloride ions. It is widely used as a source of copper in agricultural fungicides and bactericides, as well as in electroplating, chemical synthesis, and textile dyeing. Its antimicrobial properties make it valuable for controlling fungal and bacterial infections in plants. Additionally, it serves as a precursor in various industrial and laboratory applications.
Ammonium Cupric Chloride
Primary Uses
- Agriculture – Fungicide and Bactericide
- Used extensively as a copper-based fungicide and bactericide for crops such as fruits, vegetables, and ornamental plants.
- Controls fungal diseases like blight, mildew, and leaf spots by releasing copper ions toxic to fungal spores and bacteria.
- Applied as a foliar spray or soil treatment to protect plants and improve yield.
- Electroplating Industry
- Utilized as a source of copper ions in electroplating baths to deposit copper coatings on metals, enhancing corrosion resistance and electrical conductivity.
- Often part of copper sulfate and chloride plating solutions.
- Chemical Synthesis & Catalysis
- Employed in organic synthesis reactions as a catalyst or reagent.
- Used in laboratory preparations involving copper complexes.
- Textile & Leather Processing
- Acts as a mordant in dyeing processes, helping fix dyes on fabrics for improved color fastness.
- Used in leather tanning as an antimicrobial agent.
Secondary Uses
- Water Treatment
- Sometimes used in water treatment formulations to control microbial growth in industrial water systems.
- Wood Preservation
- Occasionally incorporated in wood preservatives to inhibit fungal decay and insect attack.
- Research & Analytical Chemistry
- Used as a reagent in qualitative and quantitative analysis of copper and chloride ions.
1. Basic Identification Attributes
- Chemical Name (IUPAC): Ammonium cupric chloride
- Common/Trade Names: Ammonium copper(II) chloride, Cupric ammonium chloride
- CAS Number: 1332-75-4 (varies with exact compound composition)
- HS Code: 2843.40.00
- Molecular Formula: Often represented as [Cu(NH3)4]Cl2 or variations depending on complex
- Synonyms: Tetraamminecopper(II) chloride, Cupric ammonium chloride complex
2. Physical & Chemical Properties
- Physical State: Crystalline solid
- Color & Odor: Blue-green crystals, odorless
- Melting Point: Decomposes before melting, generally >200°C
- Boiling Point: Not applicable (decomposes)
- Density: Approx. 2.4–2.7 g/cm³ (varies with hydration)
- Solubility: Soluble in water; insoluble in organic solvents
- pH Level: Slightly acidic to neutral in aqueous solution
- Vapor Pressure: Negligible
- Flash Point: Non-flammable
- Stability: Stable under normal storage conditions; sensitive to light and moisture
3. Safety & Hazard Attributes
- Hazard Class (GHS): Harmful if swallowed; causes skin and eye irritation; toxic to aquatic life
- NFPA Ratings: Health 2, Flammability 0, Reactivity 1
- Exposure Limits: No specific OSHA PEL; copper dust exposure limits generally 1 mg/m³
- Reactivity: Stable but reacts with strong acids or bases; releases toxic copper ions
- Incompatible Materials: Strong reducing agents, bases, and oxidizers
4. Storage & Handling Attributes
- Storage Conditions: Store in a cool, dry, well-ventilated area away from sunlight and moisture
- Container Type: Sealed plastic or glass containers to avoid corrosion
- Shelf Life: Typically 2–3 years if kept dry and sealed
- Special Handling: Use gloves and protective eyewear; avoid inhalation of dust or aerosols
5. Regulatory & Compliance Attributes
- Regulatory Status: Regulated under chemical safety and pesticide regulations; approval varies by country for agricultural use
- Transportation: Classified as hazardous for transport due to copper content (consult local regulations)
- Waste Disposal: Dispose of as hazardous waste due to heavy metal content, following local environmental guidelines
6. Environmental & Health Impact
- Ecotoxicity: Highly toxic to aquatic organisms and algae; potential for bioaccumulation of copper ions
- Persistence: Copper ions persist in soil and water, can accumulate in sediments
- Carcinogenicity: Not classified as carcinogenic, but prolonged exposure to copper compounds can have health risks
- Biodegradability: Inorganic; not biodegradable but copper ions can be immobilized by environmental processes
Safety Handling Precautions
- PPE: Wear gloves, safety goggles, protective clothing, and dust masks to prevent skin and eye contact and inhalation.
- Handling: Avoid dust generation; work in well-ventilated areas or use local exhaust ventilation.
- Storage: Keep container tightly closed, store in dry conditions away from incompatible materials.
- Hygiene: Wash hands thoroughly after handling; do not eat, drink, or smoke in handling areas.
First Aid Measures
- Inhalation: Move to fresh air immediately; seek medical attention if symptoms like coughing or difficulty breathing occur.
- Skin Contact: Wash skin with plenty of water; remove contaminated clothing; seek medical advice if irritation develops.
- Eye Contact: Rinse immediately with plenty of water for at least 15 minutes; consult a physician if irritation persists.
- Ingestion: Do not induce vomiting; rinse mouth and seek immediate medical attention.
Firefighting Measures
- Fire Hazards: Non-flammable but may decompose at high temperature releasing toxic copper and chlorine fumes.
- Extinguishing Media: Use water spray, foam, dry chemical, or CO₂ for surrounding fires.
- Special Precautions: Firefighters should wear self-contained breathing apparatus (SCBA) due to toxic fumes.
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