




Ammonium bicarbonate
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Ammonium bicarbonate is a white, crystalline compound with the chemical formula NH4HCO3. It is a type of inorganic salt that is commonly used in the food industry as a leavening agent for baking, as well as in the production of ceramics, dyes, and other chemicals. When heated, ammonium bicarbonate decomposes into ammonia, carbon dioxide, and water vapor, which causes dough to rise and become light and fluffy. It is also known as hartshorn or baker’s ammonia.
Ammonium bicarbonate Uses
- Food industry: Ammonium bicarbonate is commonly used as a leavening agent in baked goods such as cookies, crackers, and biscuits. It produces carbon dioxide when heated, which causes the dough to rise and gives the baked goods a light and fluffy texture.
- Agriculture: Ammonium bicarbonate is used as a fertilizer in agriculture because it provides nitrogen to plants, which is an essential nutrient for their growth.
- Pharmaceutical industry: Ammonium bicarbonate is used as an ingredient in some medications, particularly in effervescent tablets, to provide a fizzy sensation when dissolved in water.
- Chemical industry: Ammonium bicarbonate is used as a source of ammonia and carbon dioxide in the production of other chemicals such as dyes, pigments, and plastics.
- Cleaning industry: Ammonium bicarbonate is sometimes used as a cleaning agent for metals, such as brass and copper, due to its ability to remove tarnish and corrosion.
Other industries: Ammonium bicarbonate can also be used in the production of ceramics, as a blowing agent in the rubber industry, and in fire extinguishers as a non-toxic, non-corrosive, and non-conductive extinguishing agent.
COUNTRIES OF ORIGIN |
CHINA |
---|---|
APPEARANCE |
Crystalline |
AVAILABLE PACK SIZE |
25kg( Metal or Plastic Jerrycan/ Bucket, Bag, Box, Polythene bag, Carton bag) |
1. Basic Identification Attributes
- Chemical Name:
- IUPAC: Ammonium hydrogen carbonate
- Common/Trade Names: Ammonium bicarbonate, Baker's ammonia, Hartshorn
- CAS Number: 1066-33-7
- HS Code: 2836.99.90 (Other carbonates)
- Molecular Formula: NH₄HCO₃
- Synonyms: Ammonium hydrogencarbonate, ABC, Volatile salt
2. Physical & Chemical Properties
- Physical State: White crystalline powder or lumps
- Color & Odor: White; strong ammonia odor
- Boiling Point: Decomposes at 35-60°C (sublimes)
- Melting Point: Decomposes without melting
- Density/Specific Gravity: 1.586 g/cm³
- Solubility:
- Water: 11.9 g/100 mL (0°C), 36.6 g/100 mL (100°C)
- Insoluble in organic solvents
- pH Level: 7.8 (0.1M solution)
- Vapor Pressure: 59.2 mmHg at 20°C (ammonia vapor)
- Flash Point: Non-flammable
- Autoignition Temperature: Not applicable
- Viscosity: Not applicable (solid)
3. Safety & Hazard Attributes
- Hazard Class (GHS):
- Acute Toxicity (Oral) Category 4
- Skin Irritation Category 2
- Eye Irritation Category 2A
- NFPA Ratings:
- Health: 2 | Flammability: 0 | Reactivity: 1
- Exposure Limits:
- OSHA PEL: None established
- ACGIH TLV: None established
- Reactivity:
- Decomposes to ammonia, CO₂ and water when heated
- Reacts with acids and strong bases
4. Storage & Handling Attributes
- Storage Conditions:
- Cool, dry, well-ventilated area
- Below 25°C, away from moisture
- Incompatible Materials: Strong acids, bases, moisture
- Container Type: Airtight plastic or lined metal containers
- Shelf Life: 12-24 months if stored properly
- Special Handling:
- Use in well-ventilated areas
- Wear gloves and eye protection
- Avoid breathing dust
5. Regulatory & Compliance Attributes
- Regulatory Status:
- FDA: GRAS (Generally Recognized As Safe)
- EPA: Listed on TSCA Inventory
- EU: Approved food additive (E503)
- Hazard Symbols (GHS):
- Harmful if swallowed (❗)
- Causes skin and eye irritation (⚠️)
- Transportation Restrictions:
- Not classified as dangerous goods
- Waste Disposal:
- Neutralize before disposal
- Follow local regulations
6. Environmental & Health Impact
- Ecotoxicity:
- Low toxicity to aquatic organisms
- Persistence:
- Readily decomposes in environment
- Carcinogenicity/Mutagenicity:
- Not classified as carcinogenic
- Biodegradability: Fully biodegradable
Personal Protective Equipment (PPE)
- Respiratory Protection:Use a NIOSH-approved N95 respirator if handling large quantities of powder in poorly ventilated areas.
- Eye Protection:Wear safety goggles to prevent eye irritation from dust.
- Skin Protection:Use nitrile or rubber gloves to avoid skin contact.
- Clothing:Wear a lab coat or protective apron to prevent contamination.
Handling & Storage
- Avoid inhalation of dust– use in well-ventilated areas or with local exhaust ventilation.
- Prevent contact with strong acids(can release CO₂ and ammonia gas).
- Store in a cool, dry, well-ventilated area, away from heat and moisture.
- Keep containers tightly sealedto prevent decomposition and ammonia release.
- Do not store near strong oxidizers or acids(risk of hazardous reactions).
Workplace Controls
- Minimize dust generation(use closed systems or wet methods where possible).
- Avoid prolonged skin exposure– wash hands thoroughly after handling.
- Label containers clearlyto prevent accidental misuse.
Inhalation (Dust or Ammonia Fumes)
- Move to fresh air immediately.
- If breathing is difficult, administer oxygenand seek medical attention.
Skin Contact
- Remove contaminated clothing.
- Wash affected area with soap and waterfor at least 15 minutes.
- If irritation persists, consult a doctor.
Eye Contact
- Rinse immediately with lukewarm water for at least 15 minutes, holding eyelids open.
- Seek medical attentionif irritation continues.
Ingestion
- Do NOT induce vomiting.
- Rinse mouth with water and drink milk or waterto dilute.
- Seek medical advice(though low toxicity, large amounts may cause ammonia release in stomach).
Suitable Extinguishing Agents
- Water spray, CO₂, dry chemical, or foam extinguishers(standard methods).
Hazardous Decomposition Products
- Ammonia gas (NH₃)– irritating to eyes, skin, and respiratory system.
- CO₂– can displace oxygen in confined spaces.
Special Firefighting Procedures
- Wear SCBA (self-contained breathing apparatus)if large quantities are involved.
- Cool containers with waterto prevent pressure buildup from decomposition.
- Ventilate the areato disperse ammonia fumes.
- Avoid breathing decomposition products– evacuate if necessary.
Spill Cleanup:
- Wear PPE (gloves, goggles, mask).
- Sweep or vacuum (with HEPA filter) to avoid dust dispersion.
- Dispose of waste according to local regulations (not highly hazardous).
Related products
Acetaldehyde
- Chemical Structure: Acetaldehyde consists of two carbon atoms, one oxygen atom, and four hydrogen atoms. Its structure is CH3CHO, where the carbon atom in the middle is doubly bonded to an oxygen atom and singly bonded to a hydrogen atom and a methyl group (CH3).
- Occurrence: Acetaldehyde can be found naturally in various ripe fruits, coffee, and heated milk. It is also produced by the oxidation of ethanol (alcohol) by enzymes in the liver and other tissues in humans, making it an intermediate product in alcohol metabolism.
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